Showing posts with label chemistry. Show all posts
Showing posts with label chemistry. Show all posts

Friday, January 22, 2016

Cobalt: The Most Deadly Element?

Cobalt may seem innocent, peacefully hidden near the center of the periodic table, but in reality this element, commonly known for the beautiful blue pigment it produces, is deadly.

The name cobalt is sinister in itself. It comes from the German word for the element, Kobold, which means “goblin” or “evil spirit.” German miners gave cobalt this name since mining cobalt was very dangerous. Mining any element is hazardous to some degree but cobalt is particularly nasty since a toxic gas (arsenic trioxide) often occurs with cobalt in nature
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Cobalt is still mined today, mainly for use in smartphones. No doubt modern miners there would agree that Kobold is a suitable name. Cobalt miners, often children, work in perilous conditions, risking permanent lung damage earning about a dollar a day. Cobalt is in high demand due to its value as a component of super alloys, metal alloys that resist rusting and retain their properties at high temperatures. Super alloys have a variety of uses including forming parts of electronics and jet engines.

Cobalt isn’t only dangerous to miners. Cobalt-60, a radioactive isotope of cobalt, could potentially wipe out the entire human race. Leo Szilard, a scientist who worked on the Manhattan Project, figured out that an explosion of a cobalt-60 dirty bomb would kill all life in the vicinity of the explosion once it exploded, and would continue killing all life that ventured in the area for about 90 years. A cobalt-60 dirty bomb kills with heat like a normal nuclear bomb, but it has a hidden weapon that keeps it deadly for decades: gamma radiation.

A plastic isotope container containing cobalt-60
image used under creative commons

Most radioactive elements emit gamma rays for a few days, but cobalt is special. It keeps emitting deadly gamma rays for decades. These gamma rays mix up the chromosomes in our white blood cells either killing them or giving them cancer, making us vulnerable to disease. Szilard estimated that if one tenth of an ounce of cobalt-60 was sprinkled over every square mile of earth, all of humankind would perish. Thankfully no one has attempted to make cobalt-60 nuclear weapons yet, as far as we know.

Cobalt-60, despite its dangers, can also be used to help humans. Its radioactive properties are used to treat cancer, preserve food through food irradiation, and produce powerful X-rays to see through metals.

These are modern uses of cobalt, but humans have been using non-radioactive isotopes of cobalt since ancient times. Back then, cobalt was mainly used for dye. The ancient Chinese used cobalt blue in their pottery glazes. The ancient Egyptians probably used cobalt too since a small glass object colored with cobalt was found in Pharaoh Tutankhamen’s tomb. In addition to producing pretty blue dye, cobalt is one of the three naturally occurring magnetic elements
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The alchemists used cobalt in their experiments, but they attributed its properties and beautiful blue color to copper or bismuth. It wasn’t until 1730 that Georg Brandt discovered cobalt to be a unique element making cobalt the first element discovered that the alchemists hadn’t already isolated and named.
Cobalt Blue
a public domain image

The earliest use of cobalt, long before Georg Brandt or even the ancient Chinese, is the element’s use in the human body. Cobalt is vital to human health as a trace metal. We need it to form enzymes and produce vitamin B-12. It’s kind of crazy that one isotope of cobalt could kill us all, but we need another to survive.



Friday, February 20, 2015

Cyanotype Printing Experiment (somewhat successful)

Last week I went to a program for teens at the Metropolitan Museum of Art about photography. At first I was a little nervous about this workshop. Photography is not really my thing, and the only photos I take are for this blog. But then, I found out that part of the workshop was on the science of photo preservation. Once I found that out, I started to get excited. "Science," I thought "Yes, I can do this!"
My original cyanotype

In the photo preservation class, we made cyanotype prints. This printing process was invented by Sir John Herschel in 1842 when he realized that ferric (iron) salts, in combination with some other salts, could be reduced to a ferric state by exposing them to ultraviolet light. In this state, the salts could be used to create a blue and white image. In that same century, Anna Atkins published the first ever book with photographs, instead of drawn illustrations, using cyanotype prints of algae.

Cyanotype in sodium bicarbonate
I used lace, a feather, printed napkins, ribbons, and a leaf to make a design for my print. Cyanotypes can be exposed using sunlight, but in my class we used a UV ray machine since we were in a photography lab, and it happened to be late afternoon on a winter day when UV rays would be insufficient.

The bleached cyanotype
Cyanotypes have a blue background and white images. However I did not want my print to be just plain blue and white. Luckily one of the cool things about cyanotypes is that they can be bleached using sodium carbonate, or sodium bicarbonate (baking soda) and then dyed a new color with tea or coffee. The sodium carbonate or bicarbonate breaks down the iron so that the tannin in the dye can latch on more easily.

Cyanotype in the tea
I used sodium bicarbonate to bleach my print. The fact that sodium carbonate and bicarbonate bleach cyanotypes shows that base environments are not good for storing photographs, as they might fade the photos.

The dyed cyanotype.
Not exactly what I envisioned.
After bleaching my cyanotype, I soaked it in black tea for about 24 hours. The dying process did not go as well as I planned as the whole paper turned brown, not just the background.

Well, I guess I'll just have to try again to see if I can get a nice brown and white print!